CAS Number99105-77-8
SynonymsMikado; SC0051; chlormesulone; 2-[2-Chloro-4-(methylsulfonyl)benzoyl]-1,3-cyclohexanedione; sulcotrione; 2-[2-chloro-4-(methanesulfonyl)benzoyl]cyclohexane-1,3-dione; L6V CVTJ BVR BG DSW1; GALLEON; CHLORMESULON; 2-(2-chloro-4-methylsulfonylbenzoyl)-cyclohexane-1,3-dione; 2-(2-chloro-4-methylsulphonylbenzoyl)cyclohexane-1,3-dione; 2-(2-chloro-4-(methylsulfonyl)benzoyl)-1,3-cyclohexanwdione; 2-(2-Chlor-4-(methylsulfonyl)-benzoyl)-1,3-cyclohexandion; 2-(2-chloro-4-mesylbenzoyl)-cyclohexane-1,3-dione; 2-(2-Chloro-4-methanesulfonylbenzoyl)-cyclohexane-1,3-dione; ICIA0051; 2-(2-Chloro-4-mesylbenzoyl)cyclohexane-1,3-dione; 2-[2-chloro-4-(methylsulfonyl)-benzoyl]-1,3-cyclohexanedione; SULCOTRIONE,MESOTRIONE
Molecular FormulaC14H13ClO5S
Molecular Weight328.77
Purity98.00%
Density1.4±0.1 g/cm3
Boiling Point574.5±50.0 °C at 760 mmHg
Melting Point139ºC
Symbol
Signal WordWarning
| Chemical & Physical Properties | |
|---|---|
| CAS Number | 99105-77-8 |
| Catalog No. | 2A-9049582 |
| Chinese Name | 磺草酮 |
| Synonyms | Mikado; SC0051; chlormesulone; 2-[2-Chloro-4-(methylsulfonyl)benzoyl]-1,3-cyclohexanedione; sulcotrione; 2-[2-chloro-4-(methanesulfonyl)benzoyl]cyclohexane-1,3-dione; L6V CVTJ BVR BG DSW1; GALLEON; CHLORMESULON; 2-(2-chloro-4-methylsulfonylbenzoyl)-cyclohexane-1,3-dione; 2-(2-chloro-4-methylsulphonylbenzoyl)cyclohexane-1,3-dione; 2-(2-chloro-4-(methylsulfonyl)benzoyl)-1,3-cyclohexanwdione; 2-(2-Chlor-4-(methylsulfonyl)-benzoyl)-1,3-cyclohexandion; 2-(2-chloro-4-mesylbenzoyl)-cyclohexane-1,3-dione; 2-(2-Chloro-4-methanesulfonylbenzoyl)-cyclohexane-1,3-dione; ICIA0051; 2-(2-Chloro-4-mesylbenzoyl)cyclohexane-1,3-dione; 2-[2-chloro-4-(methylsulfonyl)-benzoyl]-1,3-cyclohexanedione; SULCOTRIONE,MESOTRIONE |
| Molecular Formula | C14H13ClO5S |
| Molecular Weight | 328.77 |
| Purity | 98.00 |
| Density | 1.4±0.1 g/cm3 |
| Boiling Point | 574.5±50.0 °C at 760 mmHg |
| Melting Point | 139ºC |
| Storage Condition | room temperature |
| Application | Sulcotrione is a beta-triketone herbicide that inhibits hydroxyphenylpyruvate dioxygenase (HPPD). |
| HTC | 2930909056 |
| PubChem ID | 329757134 |
| MDL Number | MFCD01632349 |
| SMILES | CS(=O)(=O)c1ccc(c(Cl)c1)C(=O)C2C(=O)CCCC2=O |
| InChI | 1S/C14H13ClO5S/c1-21(19,20)8-5-6-9(10(15)7-8)14(18)13-11(16)3-2-4-12(13)17/h5-7,13H,2-4H2,1H3 |
| InChI Key | PQTBTIFWAXVEPB-UHFFFAOYSA-N |
| Beilstein/REAXYS | 8155739 |
| NACRES Code | NA.24 |
| UNSPSC | 41116107 |
| Hazard Symbols | transportation |
| Bioactivity | Sulcotrione is a β-triketone herbicide which can inhibit hydroxyphenylpyruvate dioxygenase (HPPD). Related Catalog Signaling Pathways >> Others >> Others Research Areas >> Others Target HPPD[1] In Vitro The results show that sulcotrione behaves as time-independent reversible inhibitor. Similar results are previously described for natural β-triketones, and for the synthetic β-triketone NTBC. However it is the first time that such behavior is observed using a purified hydroxyphenylpyruvate dioxygenase (HPPD) and a synthetic β-triketone, namely sulcotrione. Inhibition kinetic analysis, performing with 3 hydroxyphenylpyruvate (HPP) and sulcotrione concentrations, show that the apparent KM increasing with sulcotrione concentration. This behavior is consistent with the data present in the literature, describing sulcotrione as a competitive inhibitor of HPPD[1]. Kinase Assay Electrochemical behavior of sulcotrione at 0.2 mg/L is characterized by cyclic voltammetry. Preliminary HPPD inhibition assays are performed by incubating the enzyme during time periods ranging from 2 to 10 min in presence of sulcotrione at differnt concentrations[1]. References [1]. Rocaboy-Faquet E, et al. A novel amperometric biosensor for ß-triketone herbicides based on hydroxyphenylpyruvatedioxygenase inhibition: A case study for sulcotrione. Talanta. 2016;146:510-6. Chemical & Physical Properties Density 1.4±0.1 g/cm3 Boiling Point 574.5±50.0 °C at 760 mmHg Melting Point 139ºC Molecular Formula C14H13ClO5S Molecular Weight 328.768 Flash Point 301.2±30.1 °C Exact Mass 328.017212 PSA 93.73000 LogP 0.21 Vapour Pressure 0.0±1.6 mmHg at 25°C Index of Refraction 1.572 InChIKey PQTBTIFWAXVEPB-UHFFFAOYSA-N SMILES CS(=O)(=O)c1ccc(C(=O)C2C(=O)CCCC2=O)c(Cl)c1 |
| Use of | Sulcotrione is a β-triketone herbicide which can inhibit hydroxyphenylpyruvate dioxygenase (HPPD). Properties Articles28 Name sulcotrione Synonym More Synonyms sulcotrione Biological Activity Description Sulcotrione is a β-triketone herbicide which can inhibit hydroxyphenylpyruvate dioxygenase (HPPD). Related Catalog Signaling Pathways >> Others >> Others Research Areas >> Others In Vitro The results show that sulcotrione behaves as time-independent reversible inhibitor. Similar results are previously described for natural β-triketones, and for the synthetic β-triketone NTBC. However it is the first time that such behavior is observed using a purified hydroxyphenylpyruvate dioxygenase (HPPD) and a synthetic β-triketone, namely sulcotrione. Inhibition kinetic analysis, performing with 3 hydroxyphenylpyruvate (HPP) and sulcotrione concentrations, show that the apparent KM increasing with sulcotrione concentration. This behavior is consistent with the data present in the literature, describing sulcotrione as a competitive inhibitor of HPPD[1]. References [1]. Rocaboy-Faquet E, et al. A novel amperometric biosensor for ß-triketone herbicides based on hydroxyphenylpyruvatedioxygenase inhibition: A case study for sulcotrione. Talanta. 2016;146:510-6. Chemical & Physical Properties Exact Mass 328.017212 PSA 93.73000 Index of Refraction 1.572 InChIKey PQTBTIFWAXVEPB-UHFFFAOYSA-N |
| Tax Rebate | 9.0% |
| Supervision | S. Import and export pesticide registration certificate |
| Transport Info | Shipping Name: UN |
| MSDS Transport Info | Module 14. Shipping information 14.1 United Nations number European Land Transport Danger Regulations: 3077 International Maritime Transport Danger Regulations: 3077 International Air Transport Danger Regulations: 3077 14.2 United Nations shipping name European land transport hazard regulations: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Sulcotrione) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Sulcotrione) International air transport hazard regulations: Environmentally hazardous substance, solid, n.o.s. (Sulcotrione) 14.3 Transport hazard categories European land transport Dangerous Regulations: 9 International sea transport Dangerous Regulations: 9 International air transport Dangerous Regulations: 9 14.4 Package group European Land Transport Danger Regulations: III International Maritime Transport Danger Regulations: III International Air Transport Danger Regulations: III 14.5 Environmental hazards European Land Transport Dangerous Regulations: Yes International Maritime Transport Dangerous Regulations International Air Transport Dangerous Regulations: Yes Marine Pollutants (Yes/No): Yes 14.6 Special precautions further information Dangerous goods are individually packaged, with liquids exceeding 5 liters or solids exceeding 5 kilograms. The outer packaging of each independent package and the combined independent inner package must have EHS on it. Identification (according to European ADR Regulation 2.2.9.1.10, IMDG Regulation 2.10.3), |
| Related Products in Agrochemical Intermediates | ||
|---|---|---|
| Haloxyfop-etotyl | 87237-48-7 | 2A-9049449 |
| 4-(2,4-Dichlorophenyl)-1H-pyrrole-3-carbonitrile | 87388-06-5 | 2A-9049465 |
| Ethyl 2,4,5-trifluorobenzoylacetate | 98349-24-7 | 2A-9049498 |
| 2,4-Dichloro-5-methoxyaniline | 98446-49-2 | 2A-9049510 |
| Benoxacor | 98730-04-2 | 2A-9049543 |
| 4-[[5,7-dihydroxy-2,2-dimethyl-8-(2-methylpropanoyl)chromen-6-yl]methy l]-3,5-dihydroxy-6,6-dimethyl-2-(2-methylpropanoyl)cyclohexa-2,4-dien- 1-one | 10-00-4 | 2A-9049590 |
| Bensulfuron | 99283-01-9 | 2A-9049599 |
| Cloquintocet-mexyl | 99607-70-2 | 2A-9049642 |
| Ethyl 1-(2,4-difluorophenyl)-7-chloro-6-fluoro-4-oxopyridino[2,3-b]pyridine-3-carboxylate | 100491-29-0 | 2A-9049729 |
| 2-(2,4-Dichloro-5-nitrophenyl)-1,2-dihydro-5-methyl-3H-1,2,4-triazol-3-one | 100563-34-6 | 2A-9049740 |
| Browse all Agrochemical Intermediates products » | ||
Phone:
630-322-8886
630-322-8887
Email:
Office Locations:
Chicago, IL, USA
San Francisco, CA, USA
EN
SDS