CAS Number13250-12-9
SynonymsEINECS 236-232-6; D-Valinol; (R)-(-)-sec-ButylaMine; MFCD07776991
Molecular FormulaC2H5CH(NH2)CH3
Molecular Weight73.14
Purity99%
Density0.72
Boiling Point63 °C (lit.)
Melting Point-104ºC
AppearanceTransparent colorless liquid
EINECS236-232-6
Symbol
Signal WordWarning
| Chemical & Physical Properties | |
|---|---|
| CAS Number | 13250-12-9 |
| Catalog No. | 2A-9035454 |
| Chinese Name | (R)-(-)-2-氨基丁烷 |
| Synonyms | EINECS 236-232-6; D-Valinol; (R)-(-)-sec-ButylaMine; MFCD07776991 |
| Molecular Formula | C2H5CH(NH2)CH3 |
| Molecular Weight | 73.14 |
| Purity | 99 |
| Density | 0.72 |
| Boiling Point | 63 °C (lit.) |
| Melting Point | -104ºC |
| Appearance | Transparent colorless liquid |
| Storage Condition | Sealed at room temperature, cool, ventilated and d |
| Packaging | II |
| EINECS | 236-232-6 |
| HTC | 2921199090 |
| PubChem ID | 24857863 |
| MDL Number | MFCD00064416 |
| SMILES | CC[C@@H](C)N |
| InChI | 1S/C4H11N/c1-3-4(2)5/h4H,3,5H2,1-2H3/t4-/m1/s1 |
| InChI Key | BHRZNVHARXXAHW-SCSAIBSYSA-N |
| Beilstein/REAXYS | 1718761 |
| NACRES Code | NA.22 |
| UNSPSC | 12352116 |
| Hazard Symbols | 3 |
| MSDS | msds/35454_1_13250_12_9.pdf |
| Use of | Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Section 7 - HANDLING and STORAGE Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Wear appropriate protective gloves to prevent skin exposure. Wear appropriate protective clothing to prevent skin exposure. Respirators: Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: amine-like pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Autoignition Temperature: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Molecular Formula: C4H11N Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, ignition sources, excess heat, strong oxidants. Incompatibilities with Other Materials: Acids, acid chlorides, acid anhydrides, carbon dioxide, strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION CAS# 13250-12-9 unlisted. Not available. Carcinogenicity: (R)-(-)-2-Aminobutane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S.* Hazard Class: 3 (8) UN Number: 2733 Packing Group: II Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S. Hazard Class: 3.1 UN Number: 2733 Packing Group: II Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S. Hazard Class: 3 UN Number: 2733 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: F C N Risk Phrases: R 11 Highly flammable. R 50 Very toxic to aquatic organisms. Safety Phrases: S 9 Keep container in a well-ventilated place. S 16 Keep away from sources of ignition - No S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 28A After contact with skin, wash immediately with plenty of water. S 33 Take precautionary measures against static discharges. and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 13250-12-9: No information available. None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 13250-12-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL CAS# 13250-12-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION Safety Information GHS02, GHS05, GHS07, GHS09 Signal Word Danger Hazard Statements H225-H302 + H332-H314-H400 Precautionary Statements P210-P273-P280-P305 + P351 + P338-P310 Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US) Hazard Codes F:Flammable;C:Corrosive;N:Dangerousfortheenvironment; RIDADR UN 2733 WGK Germany 3 Packaging Group II Hazard Class 3 HS Code 2921199090 Synthetic Route sec-butylamine 33966-50-6 Sodium 2-oxopro... (R)-()-sec-Buty... 13250-12-9 Literature: Hanson, Ronald L.; Davis, Brian L.; Chen, Yijun; Goldberg, Steven L.; Parker, William L.; Tully, Thomas P.; Montana, Michael A.; Patel, Ramesh N. Advanced Synthesis and Catalysis, 2008 , vol. 350, # 9 p. 1367 - 1375 vinyl acetate sec-butylamine 33966-50-6 (S)-(+)-2-Amino... (R)-()-sec-Buty... 13250-12-9 Literature: Journal of the Brazilian Chemical Society, , vol. 23, # 9 p. 1688 - 1697 Isopropenyl ace... sec-butylamine 33966-50-6 (S)-(+)-2-Amino... (R)-()-sec-Buty... 13250-12-9 Literature: Journal of the Brazilian Chemical Society, , vol. 23, # 9 p. 1688 - 1697 Precursor & DownStream Precursor 7 CAS#:33966-50-6 sec-butylamine CAS#:113-24-6 Sodium 2-oxopro... CAS#:108-05-4 vinyl acetate CAS#:108-22-5 Isopropenyl acetate DownStream 4 CAS#:513-49-5 (S)-(+)-2-Amino... CAS#:37143-54-7 Methoxyisopropy... CAS#:78-93-3 2-Butanone CAS#:459856-18-9 Pexacerfont |
| Tax Rebate | 9.0% |
| Supervision | none |
| Transport Info | Product name: Summary 2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
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