CAS Number1667-11-4
Synonyms4-(Chloromethyl)-1,1'-biphenyl; 4-(Chloromethyl)biphenyl; 1-(chloromethyl)-4-phenylbenzene; EINECS 216-786-5; MFCD00000917
Molecular FormulaC6H5C6H4CH2Cl
Molecular Weight202.68
Purity98%
Density1.1±0.1 g/cm3
Boiling Point322.4±21.0 °C at 760 mmHg
Melting Point70-73 °C (lit.)
Appearancepowder
EINECS216-786-5
| Chemical & Physical Properties | |
|---|---|
| CAS Number | 1667-11-4 |
| Catalog No. | 2A-9027232 |
| Chinese Name | 4-氯甲基联苯 |
| Synonyms | 4-(Chloromethyl)-1,1'-biphenyl; 4-(Chloromethyl)biphenyl; 1-(chloromethyl)-4-phenylbenzene; EINECS 216-786-5; MFCD00000917 |
| Molecular Formula | C6H5C6H4CH2Cl |
| Molecular Weight | 202.68 |
| Purity | 98 |
| Density | 1.1±0.1 g/cm3 |
| Boiling Point | 322.4±21.0 °C at 760 mmHg |
| Melting Point | 70-73 °C (lit.) |
| Appearance | powder |
| Storage Condition | Warehouse is low temperature, ventilated and dry |
| EINECS | 216-786-5 |
| HTC | 2903999090 |
| PubChem ID | 24892768 |
| MDL Number | MFCD00000917 |
| SMILES | ClCc1ccc(cc1)-c2ccccc2 |
| InChI | 1S/C13H11Cl/c14-10-11-6-8-13(9-7-11)12-4-2-1-3-5-12/h1-9H,10H2 |
| InChI Key | HLQZCRVEEQKNMS-UHFFFAOYSA-N |
| Beilstein/REAXYS | 1863327 |
| NACRES Code | NA.22 |
| UNSPSC | 12352100 |
| MSDS | msds/27232_1_1667_11_4.pdf |
| Use of | health and chemical hazard data given on this sheet. Storage:Store in closed vessels. Section8. Exposure Controls / Personal protection Engineering Controls: Use only in a chemical fume hood. Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles. General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse. Section9. Physical and chemical properties Appearance:Not specified Boiling point: Melting point:No data Flash point:No data Molecular weight: 202.7 Section10. Stability and reactivity Conditions to avoid: Heat, flames and sparks. Materials to avoid: Oxidizing agents. Possible hazardous combustion products: Carbon monoxide, hydrogen chloride. Section11. Toxicological information Section12. Ecological information Section13. Disposal consideration Arrange disposal as special waste, by licensed disposal company, in consultation with local waste disposal authority, in accordance with national and regional regulations. Section14. Transportation information Non-harzardous for air and ground transportation. Section15. Regulatory information No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, or have known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313. SECTION 16 - ADDITIONAL INFORMATION Toxicological Information CHEMICAL IDENTIFICATION RTECS NUMBER : CHEMICAL NAME : Biphenyl, 4-(chloromethyl)- CAS REGISTRY NUMBER : BEILSTEIN REFERENCE NO. : LAST UPDATED : DATA ITEMS CITED : MOLECULAR FORMULA : C13-H11-Cl MOLECULAR WEIGHT : WISWESSER LINE NOTATION : HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intraperitoneal SEX/DURATION : male 5 day(s) pre-mating TOXIC EFFECTS : Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Subcutaneous SEX/DURATION : male 5 day(s) pre-mating TOXIC EFFECTS : Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) MUTATION DATA TYPE OF TEST : Morphological transformation TEST SYSTEM : Rodent - hamster Kidney DOSE/DURATION : REFERENCE : CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 2,33,1981 Safety Information Signal Word Warning Hazard Statements H315-H319-H335 Precautionary Statements P261-P305 + P351 + P338 Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves Hazard Codes Xi:Irritant; Safety Phrases S26-S36 RIDADR NONH for all modes of transport WGK Germany 3 RTECS DV2087000 HS Code 2903999090 Synthetic Route 4-Biphenylylmethanol CAS#:3597-91-9 4-(Chloromethyl... CAS#:1667-11-4 Literature: DasGupta, Shirshendu; Murumkar, Prashant R.; Giridhar, Rajani; Yadav, Mange Ram Bioorganic and Medicinal Chemistry, 2009 , vol. 17, # 10 p. 3604 - 3617 2-(2-tert-butyl... CAS#:191097-22-0 4-(Chloromethyl... CAS#:1667-11-4 Literature: Ortho Pharmaceutical Corporation Patent: US5696117 A1, 1997 ; US 5696117 A CAS#:5728-52-9 4-(Chloromethyl... CAS#:1667-11-4 Literature: Wang, Zhentao; Zhu, Lin; Yin, Feng; Su, Zhongquan; Li, Zhaodong; Li, Chaozhong Journal of the American Chemical Society, 2012 , vol. 134, # 9 p. 4258 - 4263 Precursor & DownStream Precursor 8 CAS#:3597-91-9 4-Biphenylylmethanol CAS#:191097-22-0 2-(2-tert-butyl... CAS#:5728-52-9 CAS#:50-00-0 Formaldehyde DownStream 9 CAS#:3597-91-9 4-Biphenylylmethanol CAS#:35888-99-4 3-(4-Biphenylyl... CAS#:3218-36-8 4-Biphenylcarba... CAS#:31603-77-7 4-CYANOMETHYLBI... |
| Tax Rebate | 9.0% |
| Supervision | None MFN tariff: 5.5% Ordinary tariff: 30.0% |
| Transport Info | Product name: Summary 2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0% |
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