CAS Number2878-14-0
Synonyms2-Methylprop-2-en-1-amine; 1-amino-2-methyl-prop-2-ene; 2-Methyl-2-propen-1-amine; 2-methylallyl amine; 2-Methylprop-2-en-1-ylamine; 3-Amino-2-methyl-1-propene; EINECS 220-724-2; MFCD00053646; 2-Methylallylamine; 2-methylallyamine; methallylamine; monomethallyl amine; 2-methyl-2-propenylamine; 2-methyl prop-2-enylamine; 2-Propen-1-amine,2-methyl
Molecular FormulaC4H9N
Molecular Weight71.12
Purity98.00%
Density0.8±0.1 g/cm3
Boiling Point83.5±9.0 °C at 760 mmHg
Appearancesolid
| Chemical & Physical Properties | |
|---|---|
| CAS Number | 2878-14-0 |
| Catalog No. | 2A-9029120 |
| Chinese Name | 2-甲基烯丙胺 |
| Synonyms | 2-Methylprop-2-en-1-amine; 1-amino-2-methyl-prop-2-ene; 2-Methyl-2-propen-1-amine; 2-methylallyl amine; 2-Methylprop-2-en-1-ylamine; 3-Amino-2-methyl-1-propene; EINECS 220-724-2; MFCD00053646; 2-Methylallylamine; 2-methylallyamine; methallylamine; monomethallyl amine; 2-methyl-2-propenylamine; 2-methyl prop-2-enylamine; 2-Propen-1-amine,2-methyl |
| Molecular Formula | C4H9N |
| Molecular Weight | 71.12 |
| Purity | 98.00 |
| Density | 0.8±0.1 g/cm3 |
| Boiling Point | 83.5±9.0 °C at 760 mmHg |
| Appearance | solid |
| Storage Condition | Store airtight in a cool, dry warehouse. Keep away |
| HTC | 2921199090 |
| PubChem ID | 329778637 |
| MDL Number | MFCD00053646 |
| SMILES | CC(=C)CN |
| InChI | 1S/C4H9N/c1-4(2)3-5/h1,3,5H2,2H3 |
| InChI Key | VXDHQYLFEYUMFY-UHFFFAOYSA-N |
| NACRES Code | NA.21 |
| UNSPSC | 12352116 |
| MSDS | msds/29120_1_2878_14_0.pdf |
| Use of | Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use foam, dry chemical, or carbon dioxide. Water may be ineffective. Water may spread fire. If water is the only media available, use in flooding amounts. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Section 7 - HANDLING and STORAGE Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep away from sources of ignition. Store in a tightly closed container. Flammables-area. Keep refrigerated. (Store below 4C/39F.) Store protected from moisture. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 2878-14-0: Personal Protective Equipment Eyes: Wear chemical splash goggles. Wear appropriate protective gloves to prevent skin exposure. Wear appropriate protective clothing to prevent skin exposure. Respirators: Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: fishy ammonical pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Autoignition Temperature: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Section 10 - STABILITY AND REACTIVITY Chemical Stability: Absorbs carbon dioxide from the air. Conditions to Avoid: Ignition sources, excess heat, exposure to moist air or water. Incompatibilities with Other Materials: Strong acids, strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION CAS# 2878-14-0 unlisted. Not available. Carcinogenicity: 2-methylprop-2-en-1-ylamine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3 UN Number: 1993 Packing Group: II Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3 UN Number: 1993 Packing Group: II Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3 UN Number: 1993 Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI F Risk Phrases: R 11 Highly flammable. Safety Phrases: S 16 Keep away from sources of ignition - No S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. protection. WGK (Water Danger/Protection) CAS# 2878-14-0: No information available. None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 2878-14-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL CAS# 2878-14-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION Safety Information Hazard Codes F: Flammable;Xi: Irritant; RIDADR UN 1992 HS Code 2921199090 Synthetic Route 3-Chloro-2-meth... CAS#:563-47-3 2-Methylallylamine CAS#:2878-14-0 Literature: Weston; Ruddy; Suter Journal of the American Chemical Society, 1943 , vol. 65, p. 675 Full Text Show Details Shell Devel.Co. Patent: US2072015 , 1932 ; Full Text Show Details Shell Devel.Co. Patent: US2172822 , 1937 ; Full Text Show Details Tamele et al. Industrial and Engineering Chemistry, 1941 , vol. 33, p. 119 1-Amino-2-methy... CAS#:2854-16-2 2-Methylallylamine CAS#:2878-14-0 Literature: Adams; Cairns Journal of the American Chemical Society, 1939 , vol. 61, p. 2464,2466 2-methyl-2-prop... CAS#:104131-54-6 2-Methylallylamine CAS#:2878-14-0 Literature: Chavan, Subhash P.; Pathak, Ashok B.; Dhawane, Abasaheb N.; Kalkote Synthetic Communications, 2007 , vol. 37, # 9 p. 1503 - 1510 |
| Tax Rebate | 9.0% |
| Supervision | none |
| Transport Info | Product name: Summary 2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
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