CAS Number139-59-3
Synonyms4-phenoxy aniline; Benzenamine,4-phenoxy; EINECS 205-367-2; 4-Aminophenyl Phenyl Ether; 4-Phenoxyaniline; 4-Amino-1-phenoxybenzene; p-Aminophenyl phenyl ether; 4-phenoxyanilin; p-Phenoxyaniline; Aniline,p-phenoxy; 4-Aminodiphenyl Ether; 4-Phenoxybenzenamine; 4-phenoxy-phenylamine; MFCD00007862
Molecular FormulaC19H14FNO
Molecular Weight291.328
Purity98.00%
Density1.1±0.1 g/cm3
Boiling Point320.0±25.0 °C at 760 mmHg
Melting Point82-84 °C(lit.)
AppearanceBrown to green-brown crystalline flakes or powder
| Chemical & Physical Properties | |
|---|---|
| CAS Number | 139-59-3 |
| Catalog No. | 2A-9020828 |
| Chinese Name | 4-氨基二苯醚 |
| Synonyms | 4-phenoxy aniline; Benzenamine,4-phenoxy; EINECS 205-367-2; 4-Aminophenyl Phenyl Ether; 4-Phenoxyaniline; 4-Amino-1-phenoxybenzene; p-Aminophenyl phenyl ether; 4-phenoxyanilin; p-Phenoxyaniline; Aniline,p-phenoxy; 4-Aminodiphenyl Ether; 4-Phenoxybenzenamine; 4-phenoxy-phenylamine; MFCD00007862 |
| Molecular Formula | C19H14FNO |
| Molecular Weight | 291.328 |
| Purity | 98.00 |
| Density | 1.1±0.1 g/cm3 |
| Boiling Point | 320.0±25.0 °C at 760 mmHg |
| Melting Point | 82-84 °C(lit.) |
| Appearance | Brown to green-brown crystalline flakes or powder |
| Water Solubility | < 1 g/L (20 ºC) |
| Storage Condition | Room Temperature |
| Packaging | I; II; III |
| HTC | 2922299090 |
| MDL Number | MFCD00028070 |
| SMILES | Nc1ccc(Oc2ccccc2)cc1 |
| InChI | InChI=1S/C12H11NO/c13-10-6-8-12(9-7-10)14-11-4-2-1-3-5-11/h1-9H,13H2 |
| InChI Key | WOYZXEVUWXQVNV-UHFFFAOYSA-N |
| MSDS | msds/20828_1_139_59_3.pdf |
| Use of | Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 139-59-3: Personal Protective Equipment Eyes: Not available. Wear appropriate protective gloves to prevent skin exposure. Wear appropriate protective clothing to prevent skin exposure. Respirators: Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystalline powder Color: brown - green Odor: weak odor pH: Not available. Vapor Pressure: 13.3 hPa @180 deg C Viscosity: Not available. Autoignition Temperature: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: 385 deg C Molecular Formula: C12H11NO Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, acid anhydrides, chlorides. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION Carcinogenicity: 4-Phenoxyaniline - Not listed by ACGIH, IARC, or NTP. See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: III Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN N Risk Phrases: R 22 Harmful if swallowed. R 43 May cause sensitization by skin contact. long-term adverse effects in the aquatic environment. Safety Phrases: S 24 Avoid contact with skin. and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 61 Avoid release to the environment. Refer to special instructions/safety data sheets. WGK (Water Danger/Protection) CAS# 139-59-3: No information available. CAS# 139-59-3 is listed on Canada's NDSL List. CAS# 139-59-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL CAS# 139-59-3 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION Toxicological Information CHEMICAL IDENTIFICATION RTECS NUMBER : CHEMICAL NAME : Aniline, p-phenoxy- CAS REGISTRY NUMBER : BEILSTEIN REFERENCE NO. : LAST UPDATED : DATA ITEMS CITED : MOLECULAR FORMULA : C12-H11-N-O MOLECULAR WEIGHT : WISWESSER LINE NOTATION : HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration into the eye SPECIES OBSERVED : Rodent - rabbit MUTATION DATA TYPE OF TEST : Unscheduled DNA synthesis TEST SYSTEM : Rodent - rat Liver DOSE/DURATION : REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 204,683,1988 Safety Information Signal Word Warning Hazard Statements H302-H315-H317-H319-H335 Precautionary Statements P261-P280-P305 + P351 + P338 Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves Hazard Codes Xn:Harmful; RIDADR NONH for all modes of transport WGK Germany 3 RTECS BY7930000 Packaging Group I; II; III HS Code 2922299090 Synthetic Route Bromobenzene 4-Aminophenol 4-Phenoxyanilin... Literature: Verma, Sanny; Kumar, Neeraj; Jain, Suman L. Tetrahedron Letters, 2012 , vol. 53, # 35 p. 4665 - 4668 Iodobenzene 4-Aminophenol 4-Phenoxyanilin... Literature: Verma, Sanny; Kumar, Neeraj; Jain, Suman L. Tetrahedron Letters, 2012 , vol. 53, # 35 p. 4665 - 4668 Iodobenzene 4-Aminophenol 4-Hydroxydiphen... 4-Phenoxyanilin... Literature: Journal of the American Chemical Society, , vol. 131, # 47 p. 17423 - 17429 Precursor & DownStream Precursor 9 CAS#:108-86-1 Bromobenzene CAS#:123-30-8 4-Aminophenol CAS#:591-50-4 Iodobenzene CAS#:620-88-2 4-NITROPHENYL P... DownStream 10 CAS#:105901-53-9 1-(4-Phenoxyphe... CAS#:3529-87-1 4-phenoxyphenyl... CAS#:114279-43-5 N,N'-bis-(4-phe... CAS#:59377-19-4 4-Phenoxyphenyl... |
| Tax Rebate | 13.0% |
| Supervision | None. MFN tariff: 6.5%. Ordinary tariff: 30.0% |
| Transport Info | Product name: Summary 2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
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| Dodecyldimethylbenzylammonium chloride | 139-07-1 | 2A-9020821 |
| Aluminum acetate | 139-12-8 | 2A-9020823 |
| m-(Benzoyloxy)acetophenone | 139-28-6 | 2A-9020825 |
| Ethylenediaminetetraacetic acid disodium salt | 139-33-3 | 2A-9020826 |
| Diphenyl sulfide | 139-66-2 | 2A-9020830 |
| Pentasodium DTPA | 140-01-2 | 2A-9020833 |
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| Benzyl chloroacetate | 140-18-1 | 2A-9020836 |
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