CAS Number1070-00-4
SynonymsTri-n-octylaluminium; TRI-N-OCTYLALUMINUM; EINECS 213-964-4; Trioctylaluminum solution; Trioctylaluminum; tri(n-octyl)aluminium; Trioctylaluminium; Aluminum,trioctyl; MFCD00040497
Molecular Formula[CH3(CH2)7]3Al
Molecular Weight366.64
Purity98%
Density0.701 g/mL at 25 °C
Boiling Point126.4ºC at 760mmHg
Melting Point< -40ºC
AppearanceTransparent colorless solution
| Chemical & Physical Properties | |
|---|---|
| CAS Number | 1070-00-4 |
| Catalog No. | 2A-4182693 |
| Chinese Name | 三辛基铝溶液 |
| Synonyms | Tri-n-octylaluminium; TRI-N-OCTYLALUMINUM; EINECS 213-964-4; Trioctylaluminum solution; Trioctylaluminum; tri(n-octyl)aluminium; Trioctylaluminium; Aluminum,trioctyl; MFCD00040497 |
| Molecular Formula | [CH3(CH2)7]3Al |
| Molecular Weight | 366.64 |
| Purity | 98 |
| Density | 0.701 g/mL at 25 °C |
| Boiling Point | 126.4ºC at 760mmHg |
| Melting Point | < -40ºC |
| Appearance | Transparent colorless solution |
| Storage Condition | Sealed storage, stored in a cool, dry warehouse, a |
| HTC | 2931900090 |
| PubChem ID | 24864100 |
| MDL Number | MFCD00040497 |
| SMILES | CCCCCCCC[Al](CCCCCCCC)CCCCCCCC |
| InChI | InChI=1S/3C8H17.Al/c3*1-3-5-7-8-6-4-2;/h3*1,3-8H2,2H3; |
| InChI Key | LFXVBWRMVZPLFK-UHFFFAOYSA-N |
| NACRES Code | NA.22 |
| UNSPSC | 12352103 |
| Use of | reaction and possible flash fire. P231 + P232Handle under inert gas. Protect from moisture. P261Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P370 + P378In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P422Store contents under inert gas. Supplemental Hazard information (EU) EUH014Reacts violently with water. Hazard symbol(s) R-phrase(s) R11Highly flammable. through inhalation. aquatic environment. R62Possible risk of impaired fertility. R65Harmful: may cause lung damage if swallowed. R67Vapours may cause drowsiness and dizziness. S-phrase(s) S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S43In case of fire, use sand, dry chemical or alcohol-resistant foam. S45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61Avoid release to the environment. Refer to special instructions/ Safety data sheets. S62If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Other hazards - none Formula: C24H51Al ComponentClassificationConcentration CAS-No.110-54-3Flam. Liq. 2; Skin Irrit. 2; Repr. 50 - 100 % EC-No.203-777-62; STOT SE 3; STOT RE 2; Index-No.601-037-00-0Asp. Tox. 1; Aquatic Chronic 2; H225, H304, H315, H336, H361f, H373, H411 F, Xn, N, Repr.Cat.3, R11 - Trioctylaluminium CAS-No.1070-00-4Pyr. Liq. 1; Water-react. 1;25 - 50 % EC-No.213-964-4Skin Corr. 1B; H250, H260, H314, EUH014 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 Section4. FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. In case of eye contact If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea Indication of any immediate medical attention and special treatment needed no data available Section5. FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Dry powder Special hazards arising from the substance or mixture Carbon oxides, Aluminum oxide Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available Section6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Do not flush with water. Reference to other sections For disposal see section 13. Section7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Never allow product to get in contact with water during storage. Air and moisture sensitive. Handle and store under inert gas. Specific end use(s) no data available Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Section9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) AppearanceForm: liquid b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingno data available f) Initial boiling point and no data available boiling range h) Evaporation rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available n) Water solubilityno data available o) Partition coefficient: n- no data available octanol/water p) Auto-ignitionThe substance or mixture is not classified as pyrophoric. temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available Section10. STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions Reacts violently with water. Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. Exposure to moisture. Incompatible materials Water, Oxidizing agents, Strong oxidizing agents, Alcohols, acids, Halogens Hazardous decomposition products Other decomposition products - no data available Section11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects InhalationHarmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Vapours may cause drowsiness and dizziness. IngestionHarmful if swallowed. Causes burns. Aspiration hazard if swallowed - can enter lungs and cause damage. SkinHarmful if absorbed through skin. Causes skin burns. EyesCauses eye burns. Signs and Symptoms of Exposure Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea Additional Information RTECS: Not available Section12. ECOLOGICAL INFORMATION no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects Toxic to aquatic life. Section13. DISPOSAL CONSIDERATIONS Waste treatment methods Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal Contaminated packaging Dispose of as unused product. Section14. TRANSPORT INFORMATION ADR/RID: 3399IMDG: 3399IATA: 3399 UN proper shipping name ADR/RID: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE (Trioctylaluminium, n-Hexane) IMDG: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE (n-Hexane, Trioctylaluminium) IATA:Organometallic substance, liquid, water-reactive, flammable (n-Hexane, Trioctylaluminium) Transport hazard class(es) ADR/RID: 4.3 (3)IMDG: 4.3 (3)IATA: 4.3 (3) Packaging group ADR/RID: IIMDG: IIATA: I Environmental hazards ADR/RID: noIMDG Marine Pollutant: noIATA: no Special precautions for user no data available SECTION 15 - REGULATORY INFORMATION SECTION 16 - ADDITIONAL INFORMATION Safety Information Hazard Codes F,C,N Risk Phrases R11 Safety Phrases S9-S16-S23-S26-S45-S61-S36-S37-S39 WGK Germany 1 HS Code 2931900090 Synthetic Route Total: 1 Page Aluminium hydride CAS#:7784-21-6 CAS#:111-66-0 Tri-n-octylaluminum CAS#:1070-00-4 Literature: Gavrilenko Russian Chemical Bulletin, 2003 , vol. 52, # 5 p. 1161 - 1163 Lithium Alumini... CAS#:16853-85-3 CAS#:111-66-0 chlorodioctylal... CAS#:7325-26-0 Tri-n-octylaluminum CAS#:1070-00-4 Literature: Gavrilenko Russian Chemical Bulletin, 2003 , vol. 52, # 1 p. 168 - 169 CAS#:111-66-0 tri(butan-2-yl)... CAS#:13282-35-4 Tri-n-octylaluminum CAS#:1070-00-4 Literature: Pure and Applied Chemistry, , vol. 56, p. 1635 - 1644 Precursor & DownStream Precursor 5 CAS#:7784-21-6 Aluminium hydride CAS#:111-66-0 CAS#:16853-85-3 Lithium Alumini... CAS#:7325-26-0 chlorodioctylal... DownStream 10 CAS#:3091-25-6 Trichloro(octyl... CAS#:3542-36-7 Dichlorodioctyltin CAS#:2587-76-0 Chloro(trioctyl... CAS#:111-65-9 |
| Tax Rebate | 13.0% |
| Supervision | AB (Inbound cargo customs clearance form) |
| Transport Info | Product name: trioctyl aluminum solution |
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